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pH và nhiệt độ ảnh hưởng thế nào đến hiện tượng loang màu
  • News
  • 18/09/2025
  • Vichem

How pH and Temperature Affect Dye Unevenness

Dye unvenness is a common defect in textile finishing, creating fabric surfaces with inconsistent shades, streaks, or blotches. Fabrics such as denim, cotton, and synthetic fibers are highly prone to this issue. The root cause lies in unstable dye distribution, strongly influenced by pH and temperature. Even small deviations can alter color appearance, reduce aesthetic value, and lower commercial quality. Therefore, strict control of these two factors is essential to ensure color stability and improve textile performance.

IMPACT OF pH ON DYE UNEVENNESS

Mechanism of pH influence

In fabric dyeing, pH plays a crucial role in controlling the ionization state of dyes. When pH changes, the bonding ability of dye molecules to fibers also shifts. At low pH, dyes become highly ionized, disperse unevenly, and penetrate poorly into fibers, creating visible shade variations. Conversely, at high pH, dye affinity decreases significantly.

Dyes are easily expelled from the bath or precipitate, forming random deposits that result in blotchy appearance. In addition, pH impacts auxiliary agents. Many dispersants and surfactants remain stable only in neutral to slightly alkaline ranges. Once the bath goes beyond this range, their efficiency drops, making uneven dyeing more likely.

Common cases in practice

In industrial production, fluctuating pH values intensify shade variations. Fabrics may show horizontal streaks, long lines, or irregular blotches. In acidic environments, dyes absorb rapidly at specific points, creating dark patches next to lighter areas. In alkaline environments, poor dye fixation leads to weak wash fastness, causing shade bleeding and uneven fading.

Unstable pH also destabilizes the dye bath. Auxiliaries may coagulate, leaving irregular deposits on fiber surfaces. As a result, fabrics develop streaks and wrinkles, making them visually unappealing and unfit for export standards. This is among the toughest challenges for textile manufacturers.

Figure 1: Effect of pH on fabric dye unevenness - Vichem.vn
Figure 1: Effect of pH on fabric dye unevenness

IMPACT OF TEMPERATURE ON DYE UNEVENNESS

Mechanism of temperature influence

Temperature governs dye diffusion and reaction with fibers. When temperature rises, molecules move faster and penetrate fibers more easily. However, if heating is not well controlled, dye uptake becomes unbalanced. In the dye bath, uneven temperature distribution causes variations in dye absorption rates, leading to streaks or bands.

Not only heating but also cooling is critical. Rapid cooling can trigger dye redistribution inside fibers, distorting shades and reducing durability. Thus, maintaining uniform and stable temperature throughout the bath is essential to avoid dye unevenness.

Typical situations of dye unevenness

If temperature rises too quickly, dyes absorb locally at certain spots, creating dark patches next to pale zones. This is the main cause of localized blotching. At low temperatures, diffusion slows down, dyes fail to penetrate evenly, and fabric ends up with dull, weak shades.

Uncontrolled heating and cooling cycles, especially with reactive or disperse dyes, worsen uneven dyeing. Furthermore, when circulation is insufficient, temperature differences across the bath cause inconsistent dye uptake. The outcome is streaks and blotches, particularly evident on synthetic fibers.

Figure 2: Effect of temperature on fabric dye unevenness - Vichem.vn
Figure 2: Effect of temperature on fabric dye unevenness

SOLUTIONS TO FIX DYE UNEVENNESS CAUSED BY pH AND TEMPERATURE

Managing pH in the dyeing process

Effective pH management is vital to avoid unevenness. Buffer systems such as acetate or phosphate can maintain stable pH within neutral to slightly alkaline ranges, suitable for various fibers and dye classes. This ensures controlled ionization and uniform dye distribution.

Throughout the dyeing process, frequent measurement and adjustment are necessary. Each addition of dyes, auxiliaries, or water may shift the pH level. Continuous monitoring keeps the bath balanced, reducing the risk of streaks or blotches

Controlling heating and cooling conditions

Temperature must be increased gradually and evenly. Controlled heating prevents dyes from absorbing too quickly in certain zones, while proper cooling stabilizes dye structures inside fibers, avoiding uneven redistribution. Regular bath circulation is also required to maintain uniform temperature and concentration, ensuring smooth and consistent shades.

Supportive measures to minimize unevenness

Complementary actions enhance dyeing stability. Before bulk production, trial dyeing on small samples should be conducted to test shade uniformity under different pH and temperature conditions. This helps define optimal ranges, minimizing risks and saving costs. Moreover, adding dispersants or stabilizers for poorly soluble dyes prevents aggregation, improves distribution, and supports even coloration. These measures ensure high-quality fabrics that meet international export standards.

Figure 3: Solutions to fix dye unevenness caused by pH and temperature - Vichem.vn
Figure 3: Solutions to fix dye unevenness caused by pH and temperature

VICHEM – AUTHORIZED DISTRIBUTOR OF TEXTILE AUXILIARIES IN VIETNAM

Vichem is an authorized distributor of textile auxiliaries with full legal compliance in Vietnam. We not only provide premium-quality products but also deliver international-standard technical support and after-sales service. Our services include:

  • Technical consulting: Assisting clients in selecting suitable products for specific applications.
  • Shade testing: Vichem’s experts perform dyeing and shade control tests to ensure results meet design requirements.
  • Application support: Accompanying clients during production integration to achieve optimal performance and consistency.

For further information, please contact us via the channels below:

📞 Hotline: 08 1790 1790

📧 Email: contact@vichem.vn

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🌐 Website: www.vichem.vn

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